If there’s one thing that never seems to suffer from supply chain problems, it’s litter. It’s everywhere, easy to spot and — you’d think — pick up. Sadly, most of us seem to treat litter as somebody else’s problem, but with something like this machine vision litter mapper, you can at least be part of the solution.
For the civic-minded [Nathaniel Felleke], the litter problem in his native San Diego was getting to be too much. He reasoned that a map of where the trash is located could help municipal crews with cleanup, so he set about building a system to search for trash automatically. Using Edge Impulse and a collection of roadside images captured from a variety of sources, he built a model for recognizing trash. To find the garbage, a webcam with a car window mount captures images while driving, and a Raspberry Pi 4 runs the model and looks for garbage. When roadside litter is found, the Pi uses a Blues Wireless Notecard to send the GPS location of the rubbish to a cloud database via its cellular modem.
Cruising around the streets of San Diego, [Nathaniel]’s system builds up a database of garbage hotspots. From there, it’s pretty straightforward to pull the data and overlay it on Google Maps to create a heatmap of where the garbage lies. The video below shows his system in action.
Yes, driving around a personal vehicle specifically to spot litter is just adding more waste to the mix, but you’d imagine putting something like this on municipal vehicles that are already driving around cities anyway. Either way, we picked up some neat tips, especially those wireless IoT cards. We’ve seen them used before, but [Nathaniel]’s project gives us a path forward on some ideas we’ve had kicking around for a while.
Conventional textiles made of woven threads are highly useful materials. [Sara Alvarez] has had some success creating fabric-like materials through 3D printing, and though they’re not identical, they have some similar properties that make them unique and useful.
Fabrics are made by the weaving or knitting together many threads into a cohesive whole. [Sara]’s 3D-printed fabrics are different, since the printer can’t readily weave individual fibers together. Instead, a variety of methods are used to create similar materials.
The simplest is perhaps the chainmail method, where many small individual links join together to make a relatively rigid material. Alternatively, G-code or careful modelling can be used to create fabric-like patterns, which are printed directly in flexible material to become a fabric-like sheet. Finally, the infill method takes advantage of code inbuilt to a slicer to create a pattern that can be 3D-printed to create a fabric like material by removing the top and bottom layers of the print.
[Sara] demonstrates creating a simple “fabric” swatch using the slicer method, and demonstrates the qualities of the finished product. She also shows off various applications that can take advantage of this technique.
If you’re a 3D-printing enthusiast who also loves making clothes and apparel, consider printing up some shoes – like these we’ve seen before. Video after the break.
People have gotten much savvier about computer security in the last decade or so. Most people know that sending a document with sensitive information in it is a no-no, so many people try to redact documents with varying levels of success. A common strategy is to replace text with a black box, but you sometimes see sophisticated users pixelate part of an image or document they want to keep private. If you do this for text, be careful. It is possible to unredact pixelated images through software.
It appears that the algorithm is pretty straightforward. It simply guesses letters, pixelates them, and matches the result. You do have to estimate the size of the pixelation, but that’s usually not very hard to do. The code is built using TypeScript and while the process does require a little manual preparation, there’s nothing that seems very difficult or that couldn’t be automated if you were sufficiently motivated.
You don’t see it as often as you used to, but there have been a slew of legal and government scandals where someone redacted a document by putting a black box over a PDF so it was hidden when printed but the text was still in the document. Older wordprocessors often didn’t really delete text, either, if you knew how to look at the files. The Facebook valuation comes to mind. Not to mention that the National Legal and Policy Center was stung with poor redaction techniques.
Many years ago, I read an article about the new hotness: lithium batteries. The author opened with what he no doubt thought was a clever pop culture reference by saying that the mere mention of lithium would “strike fear in the hearts of Klingons.” It was a weak reference to the fictional “dilithium crystals” of Star Trek fame, and even then I found it a bit cheesy, but I guess he had to lead with something.
Decades later, a deeper understanding of the lore makes it clear that a Klingon’s only fear is death with dishonor, but there is a species here on earth that lives in dread of lithium: CEOs of electric vehicle manufacturing concerns. For them, it’s not the presence of lithium that strikes fear, but the relative absence of it; while it’s the 25th most abundant element in the Earth’s crust, and gigatons are dissolved into the oceans of the world, lithium is very reactive and thus tends to be diffuse, making it difficult to obtain concentrated in the quantities their businesses depend on.
As the electric vehicle and renewable energy markets continue to grow, the need for lithium to manufacture batteries will grow with it, potentially to the point where demand outstrips the mining industry’s production capability. To understand how that imbalance may be possible, we’ll take a look at how lithium is currently mined, as well as examine some new mining techniques that may help fill the coming lithium gap.
A Rocky Start
Although lithium has been known and well-characterized by chemists since the early 1800s, it was only in the middle of the previous century that commercial uses for lithium compounds were identified. The aircraft industry’s demand for stable lubricants resulted in the development of greases made from lithium soaps, and the need for high-performance but lightweight metals led the aluminum industry to employ lithium to improve the Hall-Héroult smelting process. Around the same time, doctors discovered that lithium salts can treat patients with bipolar disorder.
Even with the additional demand of the nascent nuclear industry starting in the 1940s, pretty much all the lithium needed could be supplied from small hard-rock mining operations that exploited deposits of rocks containing large crystals of lithium minerals, like spodumene, petalite, and lepidolite. These three minerals remain in high demand to this day for the production of lithium hydroxide, one of the two main lithium compounds used by industry.
The production of lithium from hard rock mines has a lot in common with other mining and refining methods we’ve discussed in this series. Ore-bearing rocks are blasted out of open-pit mines, scooped up by gigantic loaders, and trucked to a refining plant. There, the rock is reduced in size by a series of crushers and mills until it becomes a fine powder. Water is added to the powder to create a slurry known as pulp, which also contains surfactants and dispersants that make the lithium-containing minerals hydrophobic. In a shallow tank with air pumped through from the bottom, the light lithium forms a froth that floats to the top while the heavier rock particles sink.
After the lithium froth is skimmed off the flotation tank, the extra liquid is filtered off to create a concentrated but impure lithium powder that needs to be refined. The refining process depends a lot on the source minerals and desired end product, but for concentrated spodumene ore, lithium is typically leached out using a combination of sulfuric acid and sodium hydroxide. While this is a direct route with high yields, the acids and bases involved can make it environmentally problematic. Other acid-free leaching processes have been developed as a result, which is said to be the kind of process Tesla is using in their new lithium hydroxide plant being built next to their Texas Gigafactory.
Down in the Brine Mine
As mentioned before, seawater contains something like 230 billion tonnes of lithium, dissolved mainly as lithium salts. While this constitutes the bulk of the lithium on the planet, it’s far too diffuse — a mere 25 micromolar — to serve as a viable commercial source without vast expenditures of energy to extract and concentrate it. But seawater isn’t the only brine that contains lithium, and extracting the valuable metal from underground brines has become the main production method since the 1990s.
By far the biggest lithium-bearing brines are found in the “Lithium Triangle” of South America. Occupying parts of Chile, Bolivia, and Argentina, the area is home to large salt flats or salars, areas where ancient lakes or ponds evaporated, leaving behind salts and other precipitated minerals. These salt flats have built up over millions of years, leaving rich layers of minerals beneath their surfaces. And as we’ll see, the flat terrain and harsh arid conditions on the surface also play a part in the mining process.
Mining lithium brine is quite unlike any of the other methods of mining we’ve covered before, and couldn’t be simpler. Instead of digging up rocks and painstakingly isolating the material of interest, brine mining consists of injecting water down into salt deposits through deep boreholes. The water dissolves the salt deposits, creating a rich brine that can be pumped up to the surface. The brine is pumped into shallow ponds and is left in the sun to evaporate.
When most of the water in a pond has evaporated — up to two years later — the now concentrated brine is harvested. The concentrate contains a variety of elements in addition to lithium, including sodium, magnesium, phosphates, and boron. The concentrate can either be further processed on-site, or as is becoming increasingly common, shipped via pipelines to ports for transport to lithium processing plants abroad.
On the face of it, the evaporation method for lithium brine mining seems like a winner. It’s super simple, it’s powered almost exclusively by the sun, and it’s devoid of some of the impacts that a large open-pit mining operation can have. But there are still huge problems with evaporation concentration. First off, it requires vast amounts of water to create the brines in the first place, and because evaporation ponds are only practical in places where it doesn’t rain much, water is already in short supply. The water used for brine mining is also lost to the atmosphere, coming back to the surface somewhere far from the evaporation ponds. Plus, the evaporation ponds occupy unbelievably large amounts of land — some pond complexes cover an area the size of Manhattan — which makes it difficult to scale up operations. And the amount of time it takes the sun to do its work is a problem in terms of production flexibility.
A Better Way
To make the most of brine mining while mitigating its shortcomings, direct lithium extraction methods are becoming increasingly popular. In DLE, brine is pumped from underground sources, but instead of concentrating the brine by open evaporation, lithium is removed from the brine using a number of chemical and physical methods. One method is ion-exchange adsorption, where the brine is mixed with an absorbent material that preferentially binds lithium compounds over the other compounds in the brine. One class of sorbents used in DLE is known as layered double hydroxides (LDH), materials with a layered structure that allows lithium chloride in the brine to fit between the layers while excluding the potassium, magnesium, and other salts. The brine is returned to the ground, while the high-purity lithium chloride is washed off the sorbent.
Other DLE methods include membrane-separation technologies like reverse osmosis, where the brine is pumped at high pressure through membranes with pores that retain the lithium salts, or by solvent extraction, where organic solvents are used to extract the lithium. The common theme with DLE methods, though, is the fact that they are closed-loop processes — the water used to create the brine is returned to the underground formations containing the lithium. DLE plants also take up a fraction of the physical space that even a single evaporation pond would take, and they don’t rely on extreme environments like salars to work.
Best of Both Worlds
As attractive as DLE technology is, at the scale needed to be commercially viable, DLE plants still require a fair amount of energy to run. But in some places, a quirk of geology has left ample lithium deposits near a source of abundant renewable energy. In the Imperial Valley of California lies the Salton Sea, an inland saline lake that lies atop a series of active geological faults, including the famous San Andreas fault. The area is perfect for geothermal electricity production, with eleven plants currently producing 2,250 MW. Some of these geothermal plants are co-located with DLE plants, which pump up hot, lithium-rich brines that are purified using the geothermal energy produced on-site. Environmentally speaking, such plants are about as low-impact as lithium production can be, with the geothermal DLE plant being built by Australian company Controlled Thermal Resources predicted to produce 68,000 tonnes of battery-grade lithium by 2027.
With the demand for lithium set to soar, the ability to extract what we can from the limited sources we have available using the lowest amount of energy possible is becoming a challenge indeed. Geothermal DLE seems like a good start, but the number of places in the world with both the correct geochemistry and the tectonics to support such operations is limited. It’s going to take some clever engineering to get at the rest of the lithium that’s available, at least with the technology and energy resources we currently have.
[Banner photo by PABLO COZZAGLIO/AFP via Getty Images]